iron rich clay in the dirt should be enough iron supplementation. if you over do iron, you will cause your plants to have toxic levels of iron. if you have fish, that can also lead to iron toxicity in your fauna as well.
for high tech tanks micro ferts (like Plantex ) are a good source which can be measured out with known quantity. iron rich clay in the substrate provides iron via roots mainly and some via leaching into the water column. both are fine, but only one has known measured iron content (to some degree of accuracy)
I understand the point of the question but first i must mention, if you're going to talk about ferric iron you need to talk about the source of iron.
If i say only have a thin layer of laterite as an iron source, I would state a different quantity for iron shavings. One source is more pure than the other so one must be mindful of the quantity of iron in each source.
so now going back to your question
In the case of rusty nails like Lee suggested, I would only have a max of 2 nails per large plant or so. this quantity isnt set it stone. make sure not to use any stainless steel nails as they do not rust in water.
in the case of laterite, use only a thin layer then mix with a small amount of secondary layer then put the full amount of second layer then whatever else on top of that
in the case of iron ore, I dont have much information on this substance except that it is quite rich in rion like laterite so i would suggest also do a thin layer
if you have any other iron sources like rebar once again its a more pure source of iron and it depends on the surface area of the source. i would only use about 3 bars to the length of the tank or less
the main thing here is to understand that iron uptake only occurs when the plants reduce the iron from an oxide state via their roots or the water column. its best to have good rooting plants to uptake iron from the substrate.
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